Vice versa, for sure.

Latin pronunciation is very regular, either ecclesiastical or classical. If you know Spanish or Italian, the pronunciation of Latin won't be difficult, particularly with Italian. All the vowels would be pretty much the same, and if you know Italian, the same holds true of consonants. Spanish makes 'c' an 's'-sound before 'e' or 'i', IIRC, where Italian keeps the palatal 'ch' sound you would expect from ecclesiastical Latin, which also does so before 'ae' and 'oe'. 'G' is also much different in Spanish than Latin, but Italian uses the same palatal 'dj' sound before 'e', 'i', 'ae', or 'oe'. 'Gn' in Latin is like 'gn' in Italian, or 'ñ' in Spanish. Accentuation follows regular patterns too, and I know PED posted a run-down of some of the rules around here somewhere...
One of the other neat things about speaking Latin is that syntax is much freer than in English. "Canis hominem mordet", "mordet canis hominem", "hominem canis mordet" &c. all mean essentially the same thing, "The dog bites the man", but you can move words to the front of a sentence to emphasize them, where in English that'd produce weird stuff like "The man bites the dog". There are still rules, naturally, but there's a great freedom in Latin composition which you don't really find in as many modern languages.